dx.doi.org/10.1021/ma300713f

points:

(1)The self-assembled structures, nanovesicles, worm-like micelles and multicompartment micelles, formed in an emulsion polymerization process involving the controlled extension of the macroalkoxyamine with poly(4-vinylpyridine),P4VP. These structures coud be dissociated by protonation of te P4VP block. However, rebasifiction of the medium (to pH 12) did not lead to te formation of the initial morphologies, but instead classical cor-shell nanoparticls. It demonstrates the formation of our-of-equilibrium structures during the polymerization-induced self-assembly process according to the paper.

(2)The thermoresponsive block copolymers is also observed for the formation of out-of-equilibrium in polymerization-induced self-assembly process.